First of all, do you mean DVD or Blu-ray? Because they are entirely two different beasts. For one, the DVD structure has been supported for ages, but Blu-ray is really new, and it's method of navigation is not supported in full yet by any free player that I know of. However, if you just want to play the main movie (even if it is split-in-two) then just navigate to the main movie folder in windows, select the two biggest files, and drag and drop them into the Media Player Classic HC playlist.